Methyl formate

All you want to know about Methyl formate

Methyl formate
Structural formula of methyl formate
Ball-and-stick model of the methyl formate molecule
IUPAC name Methyl formate
Identifiers
CAS number 107-31-3
SMILES
 
Properties
Molecular formula HCOOCH3
Molar mass 60.05 g/mol
Density 0.98 g/cm³
Melting point

-100 °C
Boiling point

32 °C
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)
Infobox references

Methyl formate, also called methyl methanoate, is the methyl ester of formic acid. It is a clear liquid with an ethereal odor, high vapor pressure and low surface tension.

Contents

Production

In the laboratory, methyl formate can be produced by the condensation reaction of methanol and formic acid, as follows:

HCOOH + CH3OH → HCOOCH3 + H2O

Industrial methyl formate, however, is usually produced by the combination of methanol and carbon monoxide (carbonylation) in the presence of a strong base, such as sodium methoxide:[1]


CH3OH + CO → HCOOCH3


This process, practised commercially by BASF amongst other companies gives 96 % selectivity towards methyl formate, although can suffer from catalyst sensitivity to water which can commonly be present in the carbon monoxide feedstock, commonly derived from synthesis gas. Very dry carbon monoxide is therefore an essential requirement.[2]

Uses

Methyl formate is used primarily to manufacture formamide, dimethylformamide, and formic acid. Because of its high vapor pressure, it is used for quick-drying finishes. It is also used as an insecticide and to manufacture certain pharmaceuticals. A historical use of methyl formate which sometimes brings it attention was in refrigeration. Before the introduction of less toxic refrigerants, methyl formate was used as an alternative to sulfur dioxide in domestic refrigerators, such as some models of the famous GE Monitor Top. Owners of methyl formate refrigerators should keep in mind that even though they operate below atmospheric pressure, if evidence of a leak develops, they should take measures to avoid exposure to the ether-smelling liquid and vapor.

Hazards

Methyl formate has an MSDS rating of:

  • Health: 2
  • Fire: 4
  • Reactivity: 0

It is highly flammable and a spark will ignite it. It is very hazardous to the eyes and also hazardous to skin contact, ingestion, and inhalation. Safe handling of small amounts requires safety goggles, lab coat, and an approved vapor respirator.

References

 This article does not cite any references or sources.
Please help improve this article by adding citations to reliable sources. Unverifiable material may be challenged and removed. (November 2007)
  1. ^ Process Economics Reports, Review 88-1-1, Process Economics Program, SRI Consulting, California, 1999
  2. ^ W. Couteau, J. Ramioulle, US Patent US4216339

External links

 This article about an ester is a stub. You can help Wikipedia by expanding it.
Retrieved from "http://en.wikipedia.org/wiki/Methyl_formate"

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